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🧪Water Chemistry8 min read

Water Parameters Explained

A plain-English breakdown of every parameter you'll track — what it measures, why it matters, and what to do when it's off.

The Big Three (reef tanks)

Alkalinity, calcium, and magnesium are consumed together by corals, coralline algae, and other calcifying organisms. They are closely linked — changing one affects the others.

Alkalinity (also called carbonate hardness or dKH) is the most important of the three. It buffers pH and provides the carbonate that corals use to build their skeletons. Target 8–9 dKH for a stable reef. Swings of more than 0.5 dKH per day stress SPS corals significantly.

Calcium (Ca²⁺) is the mineral backbone of coral skeletons. Target 400–450 ppm. Low calcium slows growth; excess calcium (>500 ppm) precipitates out with magnesium, crashing both.

Magnesium (Mg²⁺) is the forgotten element. It keeps calcium and alkalinity in solution — without adequate magnesium, both will crash even if you're dosing correctly. Target 1250–1350 ppm.

Tips
  • Always test magnesium before troubleshooting alkalinity or calcium issues.
  • The natural ratio of Ca:Mg is roughly 1:3. If yours is far off, correct magnesium first.

pH

pH measures hydrogen ion concentration — whether water is acidic or basic. Saltwater reef tanks target 8.1–8.4; freshwater community tanks typically target 6.5–7.5 depending on species.

In a reef tank, pH is closely linked to alkalinity and CO₂ levels. Most tanks show a natural daily swing of 0.2–0.3 pH units — lower at night when plants stop photosynthesising, higher in the afternoon at peak photosynthesis. This is normal.

The most common cause of chronically low pH (7.8–8.0) in a reef tank is elevated CO₂ from poor room ventilation. Running an air line from outside the house or using a refugium with a reverse photoperiod both help.

Tips
  • Test pH at the same time each day for consistent readings — early morning is lowest, afternoon is highest.
  • A two-part or kalkwasser dosing system naturally raises pH as a side effect.

Ammonia, Nitrite, Nitrate

These three are the nitrogen cycle in numbers (see the Nitrogen Cycle guide for the full explanation).

Ammonia (NH₃/NH₄⁺): Must be zero in an established tank. Any reading above 0.25 ppm indicates a problem — dead animal, overstocking, filter failure, or insufficient cycling.

Nitrite (NO₂⁻): Must be zero in an established tank. A reading here means your bacterial colony is overwhelmed or was disrupted (chemical treatments, filter cleaning, new tank).

Nitrate (NO₃⁻): The end product of the nitrogen cycle. Not acutely toxic, but elevated levels stress fish and fuel nuisance algae. Reef: keep below 5–10 ppm for SPS. Fish-only: below 40 ppm. Freshwater planted: 5–20 ppm is acceptable and feeds plants.

Tips
  • Weekly 10–15% water changes are the simplest way to keep nitrate in check.
  • A deep sand bed or live rock provide natural denitrification (nitrate to N₂ gas).

Phosphate

Phosphate (PO₄³⁻) is a nutrient that drives algae growth. In a reef tank, target 0.03–0.1 ppm. Too low and corals become pale (nutrient-starved). Too high and coral tissue recedes, zooxanthellae multiply excessively, and nuisance algae take over.

Main phosphate sources: overfeeding, fish waste, tap water (use RODI), and some salt mixes. GFO (granular ferric oxide) media or a refugium with chaeto algae are the most common remediation tools.

Tips
  • Don't chase phosphate to zero — completely undetectable levels are bad for corals.
  • Feed small amounts frequently rather than one large daily feeding.

Salinity and Specific Gravity

Saltwater fish and invertebrates require stable salinity. Natural seawater sits at 35 ppt (1.026 specific gravity). Reef tanks are typically kept at 1.025–1.026.

Evaporation concentrates salt — salinity rises if you don't top off with fresh RODI water. An automatic top-off system (ATO) is one of the most useful investments for a reef tank, maintaining salinity passively.

A calibrated refractometer or a reliable digital salinity probe gives the most accurate readings. Swing-arm hydrometers are notoriously inaccurate and should be retired.

Tips
  • Always add RODI, never saltwater, for top-offs.
  • Calibrate your refractometer with RODI water (should read 1.000) before each use.

Temperature

Most reef organisms thrive at 25–27°C. Freshwater tropical species prefer 24–27°C depending on origin. Stable temperature is more important than hitting an exact number — a spike to 30°C or a crash to 22°C is far more damaging than running at a consistent 26°C.

In Singapore's climate, chillers are mandatory for serious reef tanks. Evaporative cooling from fans can drop temperature 2–3°C, which helps during power cuts or as a stop-gap.

Tips
  • Invest in two heaters rated at half the required wattage each — if one fails on, it won't cook the tank.
  • Set heater and chiller to maintain a 0.5°C window (e.g. chiller at 26°C, heater at 25.5°C).

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